Novel platforms for metallosupramolecular coordination studies

Yanfang, Hu; Albrecht, Markus (Thesis advisor); Weinhold, Elmar (Thesis advisor)

Aachen (2019, 2020)
Dissertation / PhD Thesis

Dissertation, RWTH Aachen University, 2019


The work of this dissertation was divided into three parts. In the first part, a series of phenanthroline-based chiral hexadentate ligands and their Eu (III) complexes were synthesized and characterized. In the second part, four dipyrrin-type ligands, as well as the corresponding complexes were developed. In the third part, a series of dinuclear triple lithium-bridged titanium (IV) helicatetype complexes were obtained and the control of the stereochemistry of hierarchically assembled helicates was investigated.